What is a conductive adhesive that uses TK silver powder?

Introduction

As explained in "What are conductive adhesives?", spherical or flake silver powder is commonly used for conductive adhesive.

KAKEN TECH has developed silver powder with a complex shape that is neither spherical nor flaky, and mass-produces it as "TK silver powder". It is known that the conductivity and physical properties of conductive adhesives change depending on the shape of the conductive particles, and we are using this TK silver powder to develop conductive adhesives with unprecedented functions.
TK silver powder has various and complicated shapes. TK silver powder has a variety of complex shapes, and our proprietary manufacturing process allows us to control the shape of the silver powder.

What is a low-silver, low-density conductive adhesive using TK silver powder?

☝Point

  • ✔  Silver conductive adhesive has low resistance and stability, but is expensive.
  • ✔  Conductive adhesives with low silver concentration using specially shaped silver powder have been put to practical use.
  • ✔  Conductive adhesives with low silver concentration are low cost and their price is not affected by market fluctuations of silver.

☝Commentary

Conductive adhesives that use silver have low resistance and stable conductivity, but their biggest disadvantage is that they are expensive because they use precious metals.
KAKEN TECH has developed a low-silver concentration, low specific gravity conductive adhesive that has good conductivity even with half the silver content of conventional adhesives, using a specially shaped TK silver powder, and succeeded in mass production for the first time in the world.
How does a low-silver, low-specific gravity conductive adhesive affect the cost? It seems to me that if the amount of silver in the adhesive is reduced, the cost will be reduced... The details are explained in the next point.
Conductive adhesives with a low silver concentration are already used in many electronic devices, not only because of the lower cost, but also because the cost is stable since the price is not affected by the market price of silver.
TK silver powder has a special chestnut-burr-like shape. Using this silver powder, we have succeeded in mass production of conductive adhesives with good electrical conductivity even at low silver concentrations.

What are the features of low silver concentration conductive adhesives?

☝Point

  • ✔  80wt% spherical silver powder and 50wt% chestnut-burr like TK silver powder have almost the same conductivity.
  • ✔  The specific gravity of the conductive adhesive of chestnut-burr like shaped TK silver powder is almost half of that of general conductive adhesives.
  • ✔  If the specific gravity is about 1/2, the volume is almost double, and you can use twice as much.

☝Commentary

Chestnut-burr like shaped TK silver powder is used in conductive adhesives with low silver concentration. The graph below shows that compared to common spherical or flake conductive particles, the chestnut-burr like shaped TK silver powder shows conductivity at low concentrations.
Chestnut-burr like shaped TK silver powder has good conductivity and low resistance even though the silver content is small; the conductivity of 50 wt% TK silver powder is almost the same as that of conductive adhesives with 80 wt% spherical silver powder.
The conductive adhesive with 50wt% (weight perctage) of chestnut-burr like TK silver powder and the conductive adhesive with 80wt% of spherical silver powder have almost the same conductivity, but the specific gravity of the conductive adhesive is 2.1 for the conductive adhesive with 50wt% chestnut-burr like TK silver powder and 4.0 for the conductive adhesive with 80wt% spherical silver powder. *1
Comparing this in terms of volume per kg, the conductive adhesive using spherical silver powder is about 250 ml, and the conductive adhesive using TK silver powder is about 480 ml.
The low silver and low specific gravity type conductive adhesive using TK silver powder is a very low-cost conductive adhesive because it has good conductivity even with a low silver content and can be applied in about twice the amount of conventional products with equivalent conductivity.

*1 Calculate based on the assumption of specific gravity of the epoxy binder is 1.2, and the specific gravity of silver is 10.5.

Shape of silver powder Chestnut-burr
like shape
Spherical
Silver content 50wt% 80wt%
Specific gravity 2.1 4.0
Image of adhesive capacity
at the same weight
Specific resistivity (ref.) 10-3Ω・cm level 10-3Ω・cm level
The specific gravity of conductive adhesive made of chestnut-burr like shaped TK silver powder is 2.1, and that of conductive adhesive made of 80wt% spherical silver powder with the same resistance value is 4.0. Comparing the volume of the same 1kg of conductive adhesive, the volume (=capacity) of the TK silver powder conductive adhesive is about twice as large.

What is the conductive mechanism of low-silver-containing conductive adhesives?

☝Point

  • ✔  Chestnut-burr like shape has more porosity than spherical shape.
  • ✔  The more voids, the lower the density and the lighter the particles become even with the same particle size.
  • ✔  The chestnut-burr like shaped silver powder can form a low-density conductive network inside the conductive adhesive.

☝Commentary

Why can electricity be conducted at a low concentration if it is in chestnut-burr like shape?

As explained in "What is a conductive adhesive", conductive particles in a conductive adhesive conduct electricity when they come into contact with each other. The chestnut-burr like shape has more voids than the spherical shape, and even though they are the same size (diameter), the density of the silver is lower and the particles are lighter.

Even if the amount of conductive particles in spherical silver powder is not enough to make contact with each other, the small density and light weight of chestnut-burr like shaped TK silver powder allows the particles to make contact with each other, forming a low-density network that conducts electricity efficiently. It can be said that the chestnut-burr like shaped TK silver powder is a convenient shape to conduct electricity with low silver concentration.

Chestnut-burr silver powderSpherical silver powder
True density10.510.5
Porosity40~70vol.%0vol.%
Bulk density1~23~5
The porosity of chestnut-burr like shaped TK silver powder is very large when the diameter is the same with the tip as the outer shell. It is a bulky particle with a small bulk density.
Bulky, chestnut-burr like shaped TK silver powder can contact each other even at low concentrations, forming a low-density network that conducts electricity. On the other hand, spherical silver powders with the same particle size cannot form a conductive path and therefore do not have conductivity.

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